PDF Ebook Chemical Kinetics and Reaction Dynamics (Dover Books on Chemistry), by Paul L. Houston, Chemistry
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Chemical Kinetics and Reaction Dynamics (Dover Books on Chemistry), by Paul L. Houston, Chemistry
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This text teaches the principles underlying modern chemical kinetics in a clear, direct fashion, using several examples to enhance basic understanding. It features solutions to selected problems, with separate sections and appendices that cover more technical applications.
Each chapter is self-contained and features an introduction that identifies its basic goals, their significance, and a general plan for their achievement. This text's important aims are to demonstrate that the basic kinetic principles are essential to the solution of modern chemical problems, and to show how the underlying question — "How do chemical reactions occur?" — leads to exciting, vibrant fields of modern research. The first aim is achieved by using relevant examples in presenting the basic material, and the second is attained by inclusion of chapters on surface processes, photochemistry, and reaction dynamics.
- Sales Rank: #341455 in Books
- Published on: 2006-11-17
- Released on: 2006-11-17
- Original language: English
- Number of items: 1
- Dimensions: 11.02" h x .73" w x 8.27" l, 1.60 pounds
- Binding: Paperback
- 348 pages
About the Author
Chairman, Department of Chemistry and Chemical Biology
Most helpful customer reviews
33 of 34 people found the following review helpful.
Yummy
By Raman
Chemical kinetics and reaction dynamics are not easy subjects, demanding quite a lot of physics in some complicated settings. Thus, it is all the more impressive that Paul Houston has managed to write this extraordinarily clear and concise text that is accessible to an advanced undergraduate.
Do not get me wrong; the prerequisites for this book are extensive. A good grasp of basic newtonian mechanics, quantum mechanics, spectroscopy, and statistical thermodynamics are musts. But nothing is needed beyond what can be expected from a good, stiff one-year course in physical chemistry.
From the first chapter on the kinetic theory of gases, Houston's focus on the physics - on keeping derivations short and clear, on connecting formulae with sound physical intuition - is striking. It does not lag as the book goes on. Houston continues with a clean exposition of empirical chemical kinetics and how to integrate and/or simplify the resulting differential equations. The grungy business of theoretical kinetics - how to kludge your way to a theoretical gas-phase reaction rate constant - is well treated after that. In the third chapter, Houston delivers an elegant and unified flux-driven treatment of transport phenomena. He gets the basic equations correct up to a numerical factor with a minimum of effort. This is beautiful; I wish chemical engineers would read this before beginning their own transport travails! There are then several chapters on the chemistry of more complicated systems, like solution-phase, solid surface-phase, and photochemical reactions. While I haven't read these, I am sure they are wonderful. The high point, in my opinion, is the final chapter on reaction dynamics. Its ongoing tacit motivation is the question, "How does a hydrogen fluoride laser work?" Read, and you will learn. In doing so, you will also become acquainted with the basic concepts in gas-phase reaction dynamics: the details of the crossed-beam molecular scattering experiment, the concept of a potential energy surface, and what these can tell us about reaction mechanisms. Throughout Houston, the emphasis on looking up from the math and seeing the physical big picture prevents the blind and frustrating equation-crunching which is all too common in the quantitative sciences.
This little book is really amazing. It takes you from a good undergraduate background to the forefront of modern chemical physics research with minimal pain and maximal excitement. Read it.
18 of 18 people found the following review helpful.
Small book! However, dense with a wealth of information.
By C. Zelaya
This book provides a very thorough introduction to chemical kinetics at an almost rigorous level. The mathematical derivations are given direct physical interpretations (something that is missing in many physical chemistry books) that are on par with physics books. Its introduction states that a full year of calculus is all that is required. I totally disagree. At the very least, the math requirements are multivariable calculus (double and triple integration appear through out the text; vector calculus {gradient , divergence, & laplacian}; partial derivatives), methods of approximation (power series & Taylor expansions), & working knowledge of ordinary & partial differential (Fick's second law of diffusion) equations are helpful in understanding how the solutions are determined. Moreover, the homework exercises present problems where Laplace transforms (small section is provided for Laplace transforms) are needed to solve the D.E.'s and P.D.E.'s. What is most surprising is that from the first page the author directly dives into kinetics with clear & precise definitions without getting sidetracked or giving any unwanted wordiness or jargon. In no way is this book what I call difficult but very accessible. The author never makes any of the subjects more difficult than they have to be in understanding the material. Mr. Houston's book stays focused to kinetics and its outcome is a book with few pages but dense & rich with material, a welcomed addition for anyone in the fields of theoretical, physical chemistry, or chemical physics. In addition, a plethora of homework problems are presented. However, it has been difficult to find the solutions manual for the problems in the book.
3 of 3 people found the following review helpful.
Helpful but not an easy read
By ecopinky
The book is good, but it is not organized/formatted well, so it was difficult to follow sometimes. Note that this book is paperback and black and white pages.
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